Luffy Uses Ryuo For The First Time [One Piece]

In what episode does Luffy use Ryuo Haki for the first time?

See answer here

finding himself in a life and death situation, Luffy out of desperation, activates Ryūō for the first time and manages to free Hyogoro and himself from the explosive collars in episode 945 (in Season 13) of the Anime One Piece, with the title: “A Grudge Over Red Bean Soup! Luffy Gets into a Desperate Situation!”.  

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Episode Summary:

Big Mom invades the Prisoner Mine in search of Red-Bean Soup (or Oshiruko) but is challenged by Queen. Queen however got over powered by Big Mom. After finding the pot with the Red-Bean Soup, Big Mom realizes that it is empty, this sends her in rage ad attacks Luffy who unknowingly admitted he was the one that ate all the soup. With the fighting ring now destroyed they are now out of bounds and the timer for the collar to activate starts. finding himself in this desperate situation, Luffy attempts to remove the collars with Haki and manages to activate Ryuo for the first time. He crushes both his and Hyogoro collar and throws them away before they could explode. Wanting to further Luffy’s Ryūō training, Hyogoro forces Luffy to defend him from Big Mom. Luffy Ryuo first time

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